Enantiotopic discrimination in the NMR spectrum of prochiral solutes in chiral liquid crystals

Author:

Lesot Philippe1234,Aroulanda Christie1234,Zimmermann Herbert5678,Luz Zeev9101112

Affiliation:

1. Laboratoire de RMN en Milieu Orienté CNRS UMR 8182

2. ICMMO

3. 91405 Orsay cedex

4. France

5. Abteilung Biophysik

6. Max-Planck-Institut für Medizinische Forschung

7. 69120 Heidelberg

8. Germany

9. Weizmann Institute of Science

10. Department of Chemical Physics

11. Rehovot 76100

12. Israel

Abstract

Theory and applications to stereo- and bio-chemistry of the discrimination of enantiotopic elements observed in the NMR spectra of prochiral solutes dissolved in chiral liquid crystals are comprehensively discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference199 articles.

1. E. E. Eliel and S. H.Wilen, Stereochemistry of Organic Compounds, J. Wiley & Sons, Wiley-Interscience, 1994

2. Stereoisomeric Relationships of Groups in Molecules

3. T. Wenzel , Discrimination of Chiral Compounds using NMR Spectroscopy, John Wiley & Sons, INC publication, Wiley-Interscience, 2007

4. Estimation of allene optical purities by nuclear magnetic resonance

5. Binuclear complexes of lanthanide(III) and silver(I) and their function as shift reagents for olefins, aromatics, and halogenated compounds

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