Conical intersections and intersystem crossings explain product formation in photochemical reactions of aryl azides
Author:
Affiliation:
1. Department of Physical Chemistry
2. Faculty of Science
3. University of Málaga
4. E-29071 Málaga
5. Spain
6. Univ. Lille
7. CNRS
8. UMR 8523 - PhLAM - Physique des Lasers Atomes et Molécules
9. F-59000 Lille
10. France
Abstract
Photochemistry of substituted aryl azides is governed by surface crossings. Internal conversion and intersystem crossing govern photodecomposition of 3-methoxyphenyl azide and 4-methoxyphenyl azide.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06974C
Reference71 articles.
1. Kinetics, Spectroscopy, and Computational Chemistry of Arylnitrenes
2. Nitrene Radical Intermediates in Catalytic Synthesis
3. Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles
4. Heteroarylcarbenes
5. Charge transfer at the nanoscale and the role of the out-of-plane vibrations in the selection rules of surface-enhanced Raman scattering
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