Conical intersections and intersystem crossings explain product formation in photochemical reactions of aryl azides-Reference-Cited by-同舟云学术

Conical intersections and intersystem crossings explain product formation in photochemical reactions of aryl azides

Published:2019 Issue:5 Volume:21 Page:2389-2396
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Soto Juan¹²³⁴⁵^ORCID,Otero Juan C.¹²³⁴⁵^ORCID,Avila Francisco J.¹²³⁴⁵^ORCID,Peláez Daniel⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Physical Chemistry

2. Faculty of Science

3. University of Málaga

4. E-29071 Málaga

5. Spain

6. Univ. Lille

7. CNRS

8. UMR 8523 - PhLAM - Physique des Lasers Atomes et Molécules

9. F-59000 Lille

10. France

Abstract

Photochemistry of substituted aryl azides is governed by surface crossings. Internal conversion and intersystem crossing govern photodecomposition of 3-methoxyphenyl azide and 4-methoxyphenyl azide.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06974C

Reference71 articles.

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