Proton conduction via lattice water molecules in oxalato-bridged lanthanide porous coordination polymers

Author:

Ishikawa Ryuta1234ORCID,Ueno Shunya1234,Yagishita Sadahiro12345,Kumagai Hitoshi674,Breedlove Brian K.1894,Kawata Satoshi1234

Affiliation:

1. Department of Chemistry

2. Fukuoka University

3. Fukuoka 814-0180

4. Japan

5. Daiichi Kigenso Kagaku Kogyo Co.

6. Toyota Central Research and Development Laboratories Inc.

7. Aichi 480-1192

8. Tohoku University

9. Sedai

Abstract

The proton conducting properties of two different structural types of porous coordination polymers [La2(ox)3(H2O)6]·4H2O (1) and [Er2(ox)3(H2O)6]·12H2O (2), where ox2− = oxalate, were investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

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2. S. Chandra , Superionic Solids: Principles and Applications, Amsterdam, North-Holland, 1981

3. P. G. Bruce , Solid State Electrochemistry, Cambridge University Press, Cambridge, 1995

4. Transport in Proton Conductors for Fuel-Cell Applications:  Simulations, Elementary Reactions, and Phenomenology

5. Alternative Polymer Systems for Proton Exchange Membranes (PEMs)

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