The influence of H-bonding on the ‘ambidentate’ coordination behaviour of the thiocyanate ion to Cd(ii): a combined experimental and theoretical study-Reference-Cited by-同舟云学术

The influence of H-bonding on the ‘ambidentate’ coordination behaviour of the thiocyanate ion to Cd(ii): a combined experimental and theoretical study

Published:2014 Issue:21 Volume:43 Page:8007-8015
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Hazari Alokesh¹²³⁴,Das Lakshmi Kanta¹²³⁴,Bauzá Antonio¹⁵⁶,Frontera Antonio¹⁵⁶,Ghosh Ashutosh¹²³⁴

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata-700 009, India

5. Universitat de les Illes Balears

6. 07122 Palma de Mallorca, Spain

Abstract

The importance of H-bonding in stabilizing the unusual S-coordination of the thiocyanate ion to Cd(ii) in hetero-metallic Cu₂Cd compounds has been established by structural analyses and DFT studies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53318B

Reference63 articles.

1. Chemistry and Biochemistry of Thiocyanic Acid and its Derivatives , ed. A. A. Newman , Academic Press , New York , 1975 , pp. 222–275

2. Chemistry of Pseudohalides , ed. A. M. Golub , H. Kohler and V. V. Skopenko , Elsevier , Amsterdam , p. 1986

3. Infrared spectra of complexes of the thiocyanate and related ions

4. Ambidentate ligands, the schizophrenics of coordination chemistry

5. Preparation, Separation, and Characterization of Ruthenium(II) Thiocyanate Linkage Isomers

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