A mononuclear divalent ytterbium hydrido complex supported by a super-bulky scorpionate ligand-Reference-Cited by-同舟云学术

A mononuclear divalent ytterbium hydrido complex supported by a super-bulky scorpionate ligand

Published:2021 Issue:78 Volume:57 Page:10047-10050
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Shi Xianghui¹^ORCID,Deng Peng¹²^ORCID,Rajeshkumar Thayalan³,Zhao Lanxiao¹²^ORCID,Maron Laurent³^ORCID,Cheng Jianhua¹²^ORCID

Affiliation:

1. State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry, Chinese Academy of Sciences No. 5625, Renmin Street, Changchun 130022, China

2. University of Science and Technology of China, Hefei, Anhui 230026, China

3. LPCNO, CNRS & INSA, UPS, Université de Toulouse 135 Avenue de Rangueil, 31077 Toulouse, France

Abstract

The first mononuclear divalent ytterbium hydride complex [(TpAd,iPr)Yb(H)(THF)] (TpAd,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (2) bearing a terminal hydrido ligand was obtained by hydrogenolysis of the benzyl precursor in hexane.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04488E

Reference40 articles.

1. F. T.Edelmann , in Comprehensive Organometallic Chemistry III , ed. R. H. Crabtree and D. M. P. Mingos , Elsevier , Oxford , 2006 , vol. 4.01, pp. 1–242

2. Non-metallocene rare-earth organometallic derivatives: synthesis, structure and application in the catalysis of transformations of unsaturated substrates

3. Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

4. A quarter-century long story of bis(alkyl) rare-earth (III) complexes

5. Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis and Reactivity of Discrete Europium(II) Hydride Complexes;Chemistry – A European Journal;2024-04-08

2. Rare-Earth-Catalyzed Regiodivergent Hydrosilylation of Aryl Alkenes;ACS Catalysis;2024-03-29

3. Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets;Journal of the American Chemical Society;2024-03-08

4. f-Block hydride complexes – synthesis, structure and reactivity;Dalton Transactions;2024

5. Multi-electron redox reactivity of a samarium(ii) hydrido complex;Chemical Science;2024