Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions-Reference-Cited by-同舟云学术

Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

Published:2015 Issue:2 Volume:6 Page:945-955
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kotani Hiroaki¹²³⁴⁵,Kaida Suzue¹²³⁴⁵,Ishizuka Tomoya¹²³⁴⁵,Sakaguchi Miyuki⁶⁷⁸⁵,Ogura Takashi⁶⁷⁸⁵,Shiota Yoshihito⁹¹⁰¹¹⁵,Yoshizawa Kazunari⁹¹⁰¹¹⁵¹²,Kojima Takahiko¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Pure and Applied Sciences

3. University of Tsukuba

4. Tsukuba

5. Japan

6. Graduate School of Life Science

7. University of Hyogo

8. Kouto

9. Institute for Materials Chemistry and Engineering

10. Kyushu University

11. Fukuoka 819-0395

12. Elements Strategy Initiative for Catalysts & Batteries

Abstract

Mechanistic insights were gained into hydrogen-atom transfer reactions from benzyl alcohol derivatives with different oxidation potentials to a highly reactive Cr(v)–oxo complex to reveal switching of reaction mechanisms.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02285H

Reference90 articles.

1. High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions

2. The Road to Non-Heme Oxoferryls and Beyond

3. Role of metal–oxo complexes in the cleavage of C–H bonds