An efficient epoxidation of terminal aliphatic alkenes over heterogeneous catalysts: when solvent matters

Author:

Palumbo C.1234ORCID,Tiozzo C.1234,Ravasio N.1234,Psaro R.1234,Carniato F.5674,Bisio C.12345,Guidotti M.1234

Affiliation:

1. CNR-Istituto di Scienze e Tecnologie Molecolari

2. Via C. Golgi 19

3. 20133 Milano

4. Italy

5. Dipartimento di Scienze e Innovazione Tecnologica and Nano-SISTEMI Interdisciplinary Centre

6. Università del Piemonte Orientale “A. Avogadro”

7. 15121 Alessandria

Abstract

With a peculiar combination of catalyst/oxidant/solvent, it is possible to obtain good yields and excellent selectivities in the epoxidation of 1-octene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference62 articles.

1. K. Bauer , D.Garbe and H.Surburg, in Common Fragrance and Flavour Materials, Wiley-VCH, Weinheim, 2001

2. S. T. Oyama , in Mechanisms in homogeneous and heterogeneous epoxidation catalysis, ed. S. T. Oyama, Elsevier, Amsterdam, 2008, pp. 5–12

3. Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis and Industrial Applications, ed. M. G. Clerici and O. A. Kholdeeva, Wiley, New Jersey, 2013

4. The Production of Propene Oxide:  Catalytic Processes and Recent Developments

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