Imido–hydrido complexes of Mo(iv): catalysis and mechanistic aspects of hydroboration reactions-Reference-Cited by-同舟云学术

Imido–hydrido complexes of Mo(iv): catalysis and mechanistic aspects of hydroboration reactions

Published:2015 Issue:43 Volume:44 Page:18945-18956
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Khalimon Andrey Y.¹²³⁴¹,Farha Philip M.¹²³⁴,Nikonov Georgii I.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Brock University

3. St. Catharines

4. Canada

Abstract

Stoichiometric reaction of complexes (ArN)Mo(H)(Cl)(PMe₃)₃ (1) and (ArN)Mo(H)₂(PMe₃)₃ (3) with nitriles and HBCat suggest that catalytic hydroboration reactions proceed via a series of agostic borylamido and borylamino complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02945G

Reference75 articles.

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5. Transition metal complexes of boron — synthesis, structure and reactivity

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