A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies-Reference-Cited by-同舟云学术

A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies

Published:2017 Issue:26 Volume:53 Page:3733-3736
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ibáñez S.¹²³⁴,Poyatos M.¹²³⁴,Peris E.¹²³⁴^ORCID

Affiliation:

1. Institute of Advanced Materials (INAM)

2. Universitat Jaume I

3. Castellón 12071

4. Spain

Abstract

A planar star-shaped tris-NHC ligand with a hexaazatriphenylene core was coordinated to gold and iridium. The tris–Au(i) complex shows enhanced catalytic activities due to the electron-deficient character of the HAT core.

Funder

Universitat Jaume I

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC00525C

Reference40 articles.

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2. Metal complexes of hexaazatriphenylene (hat) and its derivatives—from oligonuclear complexes to coordination polymers

3. Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

4. Polyaromatic N-heterocyclic carbene ligands and π-stacking. Catalytic consequences

5. Smart N-Heterocyclic Carbene Ligands in Catalysis

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