Cr3+-substitution induced structural reconfigurations in the nanocrystalline spinel compound ZnFe2O4 as revealed from X-ray diffraction, positron annihilation and Mössbauer spectroscopic studies

Author:

Thankachan Rahul Mundiyaniyil1234,Cyriac Jincemon1234,Raneesh B.5234,Kalarikkal Nandakumar12345,Sanyal D.6784,Nambissan P. M. G.91084

Affiliation:

1. School of Pure & Applied Physics

2. Mahatma Gandhi University

3. Kottayam

4. India

5. International and Inter University Centre for Nanoscience and Nanotechnology

6. Variable Energy Cyclotron Centre

7. Department of Atomic Energy

8. Kolkata 700064

9. Applied Nuclear Physics Division

10. Saha Institute of Nuclear Physics

Abstract

In an earlier work, the substitution of Zn2+ ions at the tetrahedral sites of nanocrystalline zinc ferrite (ZnFe2O4) by Ni2+ ions had been observed to cause a transformation from the normal spinel structure to the inverse one.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference40 articles.

1. J. Smit and H. P. J.Wijn, Intrinsic properties of ferrites with spinel structure, Ferrites - Physical Properties of Ferrimagnetic Oxides in Relation to Their Technical Applications, N. V. Philips' Gloeilampenfabrieken, Eindhoven, The Netherlands, 1959, ch. VIII, pp. 136–176

2. F. Scordari , Ionic Crystals, Fundamentals of Crystallography, ed. C. Giacovazzo, Oxford University Press, New York, U.S.A., 1992, ch. 6, pp. 403–464

3. V. A. M. Brabers , Progress in spinel ferrite research, Handbook of Magnetic Materials, ed. K. H. J. Buschow, North-Holland, Amsterdam, 1995, vol. 8, pp. 189–325

4. An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions

5. A comparative study on the optical limiting properties of different nano spinel ferrites with Z-scan technique

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