Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst-Reference-Cited by-同舟云学术

Dynamic parallel kinetic resolution of α-ferrocenyl cation initiated by chiral Brønsted acid catalyst

Published:2021 Issue:30 Volume:12 Page:10306-10312
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Toda Yasunori¹²³⁴⁵^ORCID,Korenaga Toshinobu⁶⁷⁸⁹⁵^ORCID,Obayashi Ren¹²³⁴⁵,Kikuchi Jun¹²³⁴⁵^ORCID,Terada Masahiro¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

6. Department of Chemistry and Biological Sciences

7. Faculty of Science and Engineering

8. Iwate University

9. Morioka 020-8551

Abstract

The dynamic parallel kinetic resolution (DPKR) of an enantiomeric α-ferrocenyl cation using a chiral phosphate anion of an acid catalyst was accomplished by the combination of the PKR and the racemization through the formation of vinylferrocene.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02122B

Reference60 articles.

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