Acidity enhancement of unsaturated bases of group 15 by association with borane and beryllium dihydride. Unexpected boron and beryllium Brønsted acids-Reference-Cited by-同舟云学术

Acidity enhancement of unsaturated bases of group 15 by association with borane and beryllium dihydride. Unexpected boron and beryllium Brønsted acids

Published:2015 Issue:3 Volume:44 Page:1193-1202
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Martín-Sómer Ana¹²³⁴⁵,Mó Otilia¹²³⁴⁵,Yáñez Manuel¹²³⁴⁵,Guillemin Jean-Claude⁶⁷⁸⁹¹⁰

Affiliation:

1. Departamento de Química

2. Facultad de Ciencias

3. Módulo 13

4. Universidad Autónoma de Madrid

5. 28049 Madrid

6. Institut des Sciences Chimiques de Rennes

7. École Nationale Supérieure de Chimie de Rennes

8. CNRS

9. UMR 6226

10. 35708 Rennes Cedex 7

Abstract

BeH₂and BH₃association with unsaturated bases of group 15 increases their acidity and changes the trend. Ethynyl : BeH₂complexes unexpectedly behave as Be acids.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02292K

Reference55 articles.

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4. Crystal and molecular structure of tris(glycinato)chromium(III) monohydrate, Cr(C2H4NO2)3.H2O

5. Nature of the donor-acceptor interaction in boron trihalide complexes. Vibrational spectra and vibrational analysis of acetonitrile-boron trichloride and acetonitrile-boron tribromide

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