Radical and diradical states of bis(molybdenocene dithiolene) complexes-Reference-Cited by-同舟云学术

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Radical and diradical states of bis(molybdenocene dithiolene) complexes

Published:2024 Issue:23 Volume:53 Page:9763-9776
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Youssef Khalil¹,Poidevin Corentin¹,Vacher Antoine¹,Fihey Arnaud¹^ORCID,Le Gal Yann¹,Roisnel Thierry¹^ORCID,Lorcy Dominique¹^ORCID

Affiliation:

1. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, F-35000 Rennes, France

Abstract

Two bimetallic complexes were synthesized and analysed through a combination of experimental and theoretical investigations. Bis-oxidized complexes exhibit, either a diradical character or a closed-shell dicationic state.

Funder

Agence Nationale de la Recherche

Région Bretagne

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00694A

Reference63 articles.

1. Reaction of Diphenylacetylene with Nickel Sulfides

2. Metal bis-1,2-dithiolene complexes in conducting or magnetic crystalline assemblies

3. Conducting Metal Dithiolene Complexes: Structural and Electronic Properties

4. Development of π-Electron Systems Based on [M(dmit)2] (M = Ni and Pd; dmit: 1,3-dithiole-2-thione-4,5-dithiolate) Anion Radicals

5. Poly (metal tetrathiooxalates): A structural and charge-transport study

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