Synthesis of new porphyrinoid dyads linked with a butenyne bridge via the Sonogashira reaction

Author:

Shkirdova Alena O.1,Tyurin Vladimir S.1ORCID,Chernyadyev Andrey Y.1,Zamilatskov Ilya A.1

Affiliation:

1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia

Abstract

Porphyrin dyads linked via a butenyne bridge were obtained for the first time. The strong interaction of units through the bridge provided energy flow between the chromophores and panchromatic light absorption, making them promising photosensitizers.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Reference56 articles.

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2. K.Kadish , R.Guilard and K. M.Smith , The Porphyrin Handbook: Multiporphyrins, Multiphthalocyanines and Arrays , Elsevier Science , 2012

3. Porphyrin dimers: A theoretical understanding of the impact of electronic coupling strength on the two-photon absorption properties

4. Porphyrin Dimers and Arrays

5. Porphyrinoids in photodynamic diagnosis and therapy of oral diseases

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