Biomimetic catalytic aerobic oxidation of C–sp(3)–H bonds under mild conditions using galactose oxidase model compound Cu<sup>II</sup>L-Reference-Cited by-同舟云学术

Biomimetic catalytic aerobic oxidation of C–sp(3)–H bonds under mild conditions using galactose oxidase model compound Cu^IIL

Published:2022 Issue:33 Volume:13 Page:9560-9568
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Xiao-Hui¹,Yu Hai-Yang¹,Huang Jia-Ying¹,Su Ji-Hu²,Xue Can¹^ORCID,Zhou Xian-Tai¹^ORCID,He Yao-Rong³,He Qian³^ORCID,Xu De-Jing¹,Xiong Chao³,Ji Hong-Bing³^ORCID

Affiliation:

1. Fine Chemical Industry Research Institute, School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, China

2. CAS Key Laboratory of Microscale Magnetic Resonance, University of Science and Technology of China, Hefei 230026, China

3. Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

Abstract

A biomimetic catalytic approach for the aerobic oxidation of C–sp(3)–H bonds using galactose oxidase model compound was developed. EPR showed that the CuI-radical intermediate species was critical for O2 activation.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Guangdong Provincial Pearl River Talents Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02606F

Reference77 articles.

1. Homogeneous Oxygenase Catalysis