Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts-Reference-Cited by-同舟云学术

Tuning the separation and coupling of corannulene trianion-radicals through sizable alkali metal belts

Published:2017 Issue:4 Volume:8 Page:3137-3145
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Spisak Sarah N.¹²³⁴⁵,Rogachev Andrey Yu.¹⁶⁷⁵,Zabula Alexander V.¹²³⁴⁵,Filatov Alexander S.¹²³⁴⁵,Clérac Rodolphe⁸⁹¹⁰¹¹¹²,Petrukhina Marina A.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University at Albany

3. State University of New York

4. Albany

5. USA

6. Illinois Institute of Technology

7. Chicago

8. CNRS

9. CRPP

10. UPR 8641

11. Pessac

12. France

Abstract

Downsizing of alkali metal belts sandwiched between triply-reduced corannulene decks allows for the fine-tune separation and magnetic coupling of C₂₀H₁₀˙³⁻radicals.

Funder

Division of Chemistry

National Science Foundation

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC05370J

Reference60 articles.

1. From charged to super-charged systems: the problem of aromaticity in polycyclic ions