Tetrahedral μ4-chloride and in situ generated octahedral μ6-sulfide templating Co8 complexes with different distortions of the cube-Reference-Cited by-同舟云学术

Tetrahedral μ4-chloride and in situ generated octahedral μ6-sulfide templating Co8 complexes with different distortions of the cube

Published:2020 Issue:30 Volume:56 Page:4236-4239
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yu You-Zhu¹²³⁴⁵,Guo Yu-Hua⁶⁷⁸⁹,Zhang Yan-Ru¹²³⁴⁵,Tian Xiu-Juan¹²³⁴⁵,Zhang Xian-Ming¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules and Magnetic Information Materials

2. Ministry of Education

3. School of Chemistry & Material Science

4. Shanxi Normal University

5. Linfen 041004

6. School of Chemical and Environmental Engineering

7. Anyang Institute of Technology

8. Anyang 455000

9. P. R. China

Abstract

Two unprecedented octanuclear Co₈ clusters with distorted cubes were synthesized using chloride and in situ generated sulfide as templates, in which strong intra-cluster antiferromagnetic interactions were found.

Funder

National Natural Science Foundation of China

Anyang Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01320J

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