Effect of total charge on the electronic structure of thiolate-protected X@Ag<sub>12</sub> superatoms (X = Ag, Au)-Reference-Cited by-同舟云学术

Effect of total charge on the electronic structure of thiolate-protected X@Ag₁₂ superatoms (X = Ag, Au)

Published:2023 Issue:8 Volume:25 Page:5955-5959
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nakamura Katsunosuke¹,Ito Shun¹,Koyasu Kiichirou¹^ORCID,Tsukuda Tatsuya¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

Gas-phase photoelectron spectroscopy revealed that the highest occupied molecular orbital of the icosahedral X@Ag12 core (X = Ag or Au) was destabilized by ~3.7 eV by the increased total negative charge from –1 to –3 due to the ligand layers.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05079J

Reference37 articles.

1. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

2. Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles

3. Insight into the Geometric and Electronic Structures of Gold/Silver Superatomic Clusters Based on Icosahedron M 13 Units and Their Alloys

4. Ligand-protected gold/silver superatoms: current status and emerging trends

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