Mechanistic insight into the formation of colloidal WS2 nanoflakes in hot alkylamine media

Author:

Scarfiello Riccardo1234ORCID,Cesari Andrea5674ORCID,Altamura Davide89104,Masi Sofia1234ORCID,Nobile Concetta1234,Balzano Federica5674ORCID,Giannini Cinzia89104ORCID,Grillo Vincenzo1112134,Tavabi Amir H.14151617,Dunin-Borkowski Rafal E.14151617,Uccello-Barretta Gloria5674ORCID,Cozzoli P. Davide123418ORCID,Rizzo Aurora1234ORCID

Affiliation:

1. CNR NANOTEC

2. Institute of Nanotechnology

3. 73100 Lecce

4. Italy

5. Department of Chemistry and Industrial Chemistry

6. University of Pisa

7. 56124 Pisa

8. IC CNR

9. Institute of Crystallography

10. I-70126 Bari

11. Centro S3

12. CNR Istituto Nanoscienze

13. 41125 Modena

14. Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons

15. Forschungszentrum Jülich

16. 52425 Julich

17. Germany

18. Department of Mathematics and Physics E. De Giorgi

Abstract

Non-hydrolytic synthesis assisted by long-chain amphiphilic surfactant is exploited to generate dimension-controllable 2D-WS2 nanoflakes in a single-step protocol, where the chemical nature and steric hindrance of the alkylamine are the key points to modulate the lateral size finally achieved.

Funder

European Union's Horizon 2020

University of Pisa

Ministero dell'Istruzione, dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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