Bifunctional iminophosphorane catalysed enantioselective sulfa-Michael addition of alkyl thiols to alkenyl benzimidazoles-Reference-Cited by-同舟云学术

Bifunctional iminophosphorane catalysed enantioselective sulfa-Michael addition of alkyl thiols to alkenyl benzimidazoles

Published:2018 Issue:34 Volume:9 Page:6969-6974
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Formica Michele¹²³⁴⁵^ORCID,Sorin Geoffroy¹²³⁴⁵^ORCID,Farley Alistair J. M.¹²³⁴⁵,Díaz Jesús⁶⁷⁸⁹¹⁰^ORCID,Paton Robert S.¹¹¹¹²¹³^ORCID,Dixon Darren J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Chemistry Research Laboratory

3. University of Oxford

4. Oxford OX1 3TA

5. UK

6. Departamento de Química Orgánica

7. Universidad de Extremadura

8. Avda. Universidad

9. s/n, 10003 Cáceres

10. Spain

11. Colorado State University

12. Fort Collins

13. USA

Abstract

The first enantioselective sulfa-Michael addition of alkyl thiols to alkenyl benzimidazoles, enabled by a bifunctional iminophosphorane (BIMP) organocatalyst, is described.

Funder

Engineering and Physical Sciences Research Council

National Science Foundation

Université Paris Descartes

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01804A

Reference88 articles.

1. Conjugate Additions to Vinyl-Substituted Aromatic N-Heterocycles