A copper coordination polymer precatalyst with asymmetric building units for selective CO2-to-C2H4electrolysis

Author:

Wen Chun Fang1,Zhou Min2,Wu Xuefeng1,Liu Yuanwei1,Mao Fangxin1,Fu Huai Qin3,Shi Yingli1,Dai Sheng4ORCID,Zhu Minghui5ORCID,Yang Shuang1ORCID,Wang Hai Feng2ORCID,Liu Peng Fei1ORCID,Yang Hua Gui1ORCID

Affiliation:

1. Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

2. Key Laboratory for Advanced Materials, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

3. Centre for Catalysis and Clean Energy, Gold Coast Campus, Griffith University, Gold Coast 4222, QLD, Australia

4. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

5. State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

Abstract

A Cu-BTC-CP precatalyst with asymmetric building units, whichin situreconstructs to low-coordinated Cu during the CO2RR, delivers an ethylene faradaic efficiency of 65.2 ± 3% at 350 mA cm−2in a flow cell.

Funder

National Key Research and Development Program of China

Science and Technology Commission of Shanghai Municipality

National Natural Science Foundation of China

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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