The role of substituents in determining the redox potential of organic electrode materials in Li and Na rechargeable batteries: electronic effects vs. substituent-Li/Na ionic interaction

Author:

Lee Sechan12345ORCID,Kwon Ji Eon12345ORCID,Hong Jihyun6789ORCID,Park Soo Young12345ORCID,Kang Kisuk12345ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. Research Institute of Advanced Materials (RIAM)

3. Seoul National University

4. Seoul 08826

5. Republic of Korea

6. Center for Energy Materials Research

7. Korea Institute of Science and Technology (KIST)

8. Seoul 02792

9. South Korea

Abstract

The competition between electronic effects and the ionic interaction is suggested as the governing factor determining the redox voltages through analysis on the voltage trend of chemically tuned Na2TP derivatives.

Funder

National Research Foundation of Korea

Korea Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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