Efficient masking of corrosion and fission products such as Ni(ii) and Pd(ii) in the presence of the minor actinide Am(iii) using hydrophilic anionic or cationic bis-triazines-Reference-Cited by-同舟云学术

Efficient masking of corrosion and fission products such as Ni(ii) and Pd(ii) in the presence of the minor actinide Am(iii) using hydrophilic anionic or cationic bis-triazines

Published:2015 Issue:44 Volume:51 Page:9189-9192
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lewis Frank W.¹²³⁴⁵,Harwood Laurence M.¹²³⁴,Hudson Michael J.¹²³⁴,Müllich Udo⁶⁷⁸⁹,Geist Andreas⁶⁷⁸⁹

Affiliation:

1. Department of Chemistry

2. The University of Reading

3. Whiteknights

4. UK

5. Department of Applied Sciences

6. Karlsruher Institut für Technologie (KIT-INE)

7. Institut für Nukleare Entsorgung

8. D-76344 Eggenstein-Leopoldshafen

9. Germany

Abstract

We report the first examples of hydrophilic 3,3′-bis(1,2,4-triazine) ligands and their application as masking agents to suppress the extraction of corrosion and fission products found in used nuclear fuel solutions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC02336J

Reference32 articles.

1. Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides

2. M. J. Hudson , F. W.Lewis and L. M.Harwood, in Strategies and Tactics in Organic Synthesis, ed. M. Harmata, Elsevier, Amsterdam, 2013, vol. 9, pp. 177–202

3. Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N-Donor Ligands

4. Trivalent Actinide and Lanthanide Separations by Tetradentate Nitrogen Ligands: A Quantum Chemistry Study

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