Alkali metal catalyzed dehydro-coupling of boranes and amines leading to the formation of a B

Alkali metal catalyzed dehydro-coupling of boranes and amines leading to the formation of a B–N bond

Published:2016 Issue:42 Volume:6 Page:35648-35653
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Harinath A.¹²³⁴,Anga Srinivas¹²³⁴,Panda Tarun K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Hyderabad

3. Sangareddy 502285

4. India

Abstract

N–H/H–B cross-dehydrogenative coupling (CDC) of boranes and amines with high conversion (>90%) and chemo-selectivity using group-1 metal salts as pre-catalysts, and under ambient conditions is presented.

Funder

Ministry of New and Renewable Energy India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA04125F

Reference40 articles.

1. The Atom Economy—A Search for Synthetic Efficiency

2. Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way

3. B. M. Trost , Atom economy: a challenge for enhanced synthetic efficiency, in Handbook of green chemistry volume 7: green synthesis, ed. C. J. Li, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2012

4. Zirconium - Phosphorus Chemistry: Strategies in Syntheses, Reactivity, Catalysis, and Utility

5. Transition-Metal-Catalyzed Dehydrocoupling: A Convenient Route to Bonds between Main-Group Elements

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