Determination of enantiomeric excess of carboxylates by fluorescent macrocyclic sensors

Author:

Akdeniz Ali1234,Minami Tsuyoshi1234,Watanabe Sagiri56789,Yokoyama Maki56789,Ema Tadashi56789,Anzenbacher Pavel1234

Affiliation:

1. Department of Chemistry and Center for Photochemical Sciences

2. Bowling Green State University

3. Bowling Green

4. USA

5. Division of Applied Chemistry

6. Graduate School of Natural Science and Technology

7. Okayama University

8. Okayama 700-8530

9. Japan

Abstract

Chiral fluorescent macrocycles enable detection of carboxylate enantiomers using naked eye, which allows for quantitative measurement of the enantiomeric excess with high accuracy (error < 1.6%).

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference70 articles.

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4. Fluorogenic and Chromogenic Chemosensors and Reagents for Anions

5. J. L. Sessler , P. A.Gale and W.Cho, in Anion Receptor Chemistry; Monographs in Supramolecular Chemistry, The Royal Society of Chemistry, Cambridge, 2006

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