Aerobic oxidation-functionalization of the aryl moiety in van Koten's pincer complex (NCN)Ni(ii)Br: relevance to carbon–heteroatom coupling reactions promoted by high-valent nickel species-Reference-Cited by-同舟云学术

Aerobic oxidation-functionalization of the aryl moiety in van Koten's pincer complex (NCN)Ni(ii)Br: relevance to carbon–heteroatom coupling reactions promoted by high-valent nickel species

Published:2022 Issue:4 Volume:46 Page:1800-1807
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Cloutier Jean-Philippe¹,Zamani Fahimeh¹,Zargarian Davit¹^ORCID

Affiliation:

1. Département de chimie, Université de Montréal, Montréal (Québec), H3C 3J7, Canada

Abstract

Treating the pincer complex (NCN)NiBr with protic substrates HX (X = OH, OR, or NR2) under aerobic conditions leads to C–X functionalization of the pincer ligand. The crucial importance of aerobic conditions for the success of this coupling reaction implies the formation of high-valent intermediates during the course of the reaction.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ05162H

Reference46 articles.

1. Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds

2. Nickel(II)-Catalyzed Direct Arylation of C–H Bonds in Aromatic Amides Containing an 8-Aminoquinoline Moiety as a Directing Group

3. Ligand Redox Effects in the Synthesis, Electronic Structure, and Reactivity of an Alkyl−Alkyl Cross-Coupling Catalyst

4. Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent

5. Carbon-Nitrogen Bond Formation by Reductive Elimination from Nickel(II) Amido Alkyl Complexes

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Taming the Lewis Superacid Al(ORF)₃ (RF=C(CF₃)₃): DFT Guided Identification of the “Stable yet Reactive” Adduct SiPr₂→Al(ORF)₃; Its Use as ORF‐ Abstractor from a “Ni‐ORF” complex;Chemistry – A European Journal;2023-04-12