Direct synthesis of a geminal zwitterionic phosphonium/hydridoborate system – developing an alternative tool for generating frustrated Lewis pair hydrogen activation systems

Author:

Yu Jiangang123,Kehr Gerald123,Daniliuc Constantin G.123,Bannwarth Christoph45673,Grimme Stefan45673,Erker Gerhard123

Affiliation:

1. Organisch-Chemisches Institut der Universität Münster Correnstraβe 40

2. 48149 Münster

3. Germany

4. Mulliken Center for Theoretical Chemistry

5. Institut für Physikalische und Theoretische Chemie

6. Universität Bonn

7. 53115 Bonn

Abstract

A convenient way to a new class of geminal Mes2PH+/B(C6F5)2H pairs is presented.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference57 articles.

1. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

2. Frustrated Lewis Pairs I, Uncovering and Understanding in Topics in Current Chemistry, ed. G. Erker and D. W. Stephan, Springer, Heidelberg, New York, Dordrecht, London, 2013, vol. 332

3. Frustrated Lewis Pairs II, Expanding the Scope in Topics in Current Chemistry, ed. G. Erker and D. W. Stephan, Springer, Heidelberg, New York, Dordrecht, London, 2013, vol. 334

4. Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

5. Frustrated Lewis pairs: Some recent developments

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