Antimony(+5) ion induced tunable intramolecular charge transfer in hypervalent antimony(<scp>v</scp>) porphyrins-Reference-Cited by-同舟云学术

Antimony(+5) ion induced tunable intramolecular charge transfer in hypervalent antimony(v) porphyrins

Published:2022 Issue:15 Volume:51 Page:5890-5903
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Holzer Noah¹,Sharma Jatan K.²^ORCID,Peterson Steven¹,Bayard Brandon J.¹,Nesterov Vladimir N.²,Karr Paul A.³,D'Souza Francis²^ORCID,Poddutoori Prashanth K.¹^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry, University of Minnesota Duluth, 1038 University Drive, Duluth, Minnesota 55812, USA

2. Department of Chemistry, University of North Texas, 1155 Union Circle, # 305070, Denton, Texas 76203-5017, USA

3. Department of Physical Sciences and Mathematics, Wayne State College, 1111 Main Street, Wayne, Nebraska 68787, USA

Abstract

Antimony(+5) insertion induces both electron-rich and electron-poor parts within the porphyrin structure resulting in a push–pull style intramolecular charge transfer.

Funder

University of Minnesota Duluth

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00675H

Reference41 articles.

1. Anion-enhanced excited state charge separation in a spiro-locked N-heterocycle-fused push-pull zinc porphyrin

2. Push–Pull Porphyrins via β‐Pyrrole Functionalization: Evidence of Excited State Events Leading to High‐Potential Charge‐Separated States