Synthesis of substituted γ- and δ-lactams based on titanocene(iii)-catalysed radical cyclisations of trichloroacetamides-Reference-Cited by-同舟云学术

Synthesis of substituted γ- and δ-lactams based on titanocene(iii)-catalysed radical cyclisations of trichloroacetamides

Published:2016 Issue:60 Volume:6 Page:55360-55365
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Diaba Faïza¹²³⁴⁵,Gómez-Bengoa Enrique⁶⁷⁸⁹,Cuerva Juan M.¹⁰¹¹¹²¹³⁹,Bonjoch Josep¹²³⁴⁵,Justicia José¹⁰¹¹¹²¹³⁹

Affiliation:

1. Laboratori de Química Orgànica

2. Facultat de Farmàcia

3. IBUB

4. Universitat de Barcelona

5. 08028-Barcelona

6. Departamento de Química Orgánica I

7. Universidad del País Vasco

8. 20018 San Sebastián

9. Spain

10. Departamento de Química Orgánica

11. Facultad de Ciencias

12. Universidad de Granada

13. 18071-Granada

Abstract

Straightforward synthesis of dehalogenated γ- and δ-lactams based on a Cp₂TiCl-catalysed radical cyclisation of trichloroacetamides under mild conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA12180B

Reference66 articles.

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2. Transition-metal-centered radicals in organic synthesis. Titanium(III)-induced cyclization of epoxy olefins

3. Intermolecular addition of epoxides to activated olefins: a new reaction

4. Free radical-mediated reduction and deoxygenation of epoxides

5. Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis

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2. Development, Scope, and Applications of Titanium(III)-Catalyzed Cyclizations to Aminated N-Heterocycles;Chemistry - A European Journal;2019-02-07

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4. Radical Cyclization of Trichloroacetamides: Synthesis of Lactams;Synthesis;2017-01-03

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