Cascade cyclization and acyl migration of propargylic esters with isocyanides: rapid access to substituted furans-Reference-Cited by-同舟云学术

Cascade cyclization and acyl migration of propargylic esters with isocyanides: rapid access to substituted furans

Published:2019 Issue:58 Volume:55 Page:8394-8397
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hu Jie¹²³⁴⁵,Fei Youwen¹²³⁴⁵,Zhao Hongbin¹²³⁴⁵,Wang Zhishuang¹²³⁴⁵,Li Chunju⁶⁷⁸⁹¹⁰^ORCID,Li Jian¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Center for Supramolecular Chemistry and Catalysis

3. College of Sciences & Institute for Sustainable Energy

4. Shanghai University

5. Shanghai 200444

6. Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry

7. Ministry of Education

8. Tianjin Key Laboratory of Structure and Performance for Functional Molecules

9. College of Chemistry

10. Tianjin Normal University

Abstract

A novel rearrangement of ester-activated propargylic acetate with isocyanide has been disclosed. This protocol enables a quick synthesis of polysubstituted furan derivatives.

Funder

Natural Science Foundation of Shanghai

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC03550H

Reference72 articles.

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2. Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates

3. Copper-Catalyzed Borylative Cyclization of o-(Cyano)phenyl Propargyl Carbonates: Synthesis of Functionalized 1-Naphthylamines

4. Asymmetric Intermolecular Heck Reaction of Propargylic Acetates and Cycloalkenes to Access Fused Cyclobutenes

5. Double Transfer of Chirality in Organocopper-Mediated bis(Alkylating) Cycloisomerization of Enediynes

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