Picosecond dynamics of hydrogen bond rearrangements during phase separation of a triethylamine and water mixture-Reference-Cited by-同舟云学术

Picosecond dynamics of hydrogen bond rearrangements during phase separation of a triethylamine and water mixture

Published:2014 Issue:6 Volume:13 Page:891-897
ISSN:1474-905X
Container-title:Photochem. Photobiol. Sci.
language:en
Short-container-title:Photochem. Photobiol. Sci.

Author:

Kajimoto Shinji¹²³⁴,Seong Nak-Hyun⁵⁶⁷⁸,Fukumura Hiroshi¹²³⁴,Dlott Dana D.⁵⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578, Japan

5. School of Chemical Sciences

6. University of Illinois at Urbana – Champaign

7. Chemical and Life Sciences Laboratory

8. Urbana, USA

Abstract

A picosecond temperature jump experiment reveals that phase separation in a liquid triethylamine (TEA)–water mixture started from hydrogen bond scission of TEA–water aggregates in TEA-rich regions and then in water-rich regions.

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/PP/C4PP00048J

Reference36 articles.

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4. Thermal phase behavior of triethylamine–water mixtures studied by near-infrared spectroscopy: band shift of the first overtone of the C–H stretching modes and the phase diagram

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