Picosecond dynamics of hydrogen bond rearrangements during phase separation of a triethylamine and water mixture
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Tohoku University
4. Sendai 980-8578, Japan
5. School of Chemical Sciences
6. University of Illinois at Urbana – Champaign
7. Chemical and Life Sciences Laboratory
8. Urbana, USA
Abstract
A picosecond temperature jump experiment reveals that phase separation in a liquid triethylamine (TEA)–water mixture started from hydrogen bond scission of TEA–water aggregates in TEA-rich regions and then in water-rich regions.
Publisher
Springer Science and Business Media LLC
Subject
Physical and Theoretical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/PP/C4PP00048J
Reference36 articles.
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3. Photo-controlled phase separation and mixing of a mixture of water and 2-butoxyethanol caused by photochromic isomerisation of spiropyran
4. Thermal phase behavior of triethylamine–water mixtures studied by near-infrared spectroscopy: band shift of the first overtone of the C–H stretching modes and the phase diagram
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