Stabilization of synthetic heme-superoxo complexes by hydrogen bonding: a still on-going quest-Reference-Cited by-同舟云学术

Stabilization of synthetic heme-superoxo complexes by hydrogen bonding: a still on-going quest

Published:2018 Issue:10 Volume:42 Page:7516-7521
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Boitrel Bernard¹²³⁴^ORCID,Le Gac Stéphane¹²³⁴^ORCID

Affiliation:

1. UMR CNRS 6226

2. Institut des Sciences Chimiques de Rennes, Université de Rennes 1

3. 35042 Rennes cedex

4. France

Abstract

The design of various types of synthetic heme models has allowed the fine tuning of the location of hydrogen bond donors around the ferrous coordination site. Through the years, it has migrated from a lateral to a quasi-apical position. Still, the unambiguous existence of an actual H-bond with the dioxygen adduct remains to be established.

Funder

Centre National de la Recherche Scientifique

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04145D

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