Palladium-catalyzed ortho-vinylation of β-naphthols with α-trifluoromethyl allyl carbonates: one-pot access to naphtho[2,1-b]furans-Reference-Cited by-同舟云学术

Palladium-catalyzed ortho-vinylation of β-naphthols with α-trifluoromethyl allyl carbonates: one-pot access to naphtho[2,1-b]furans

Published:2021 Issue:38 Volume:19 Page:8241-8245
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Priyanka Chiliveru¹²,Subbarao Muppidi¹²,Punna Nagender¹²^ORCID

Affiliation:

1. Department of Organic Synthesis & Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad - 500007, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201 002, India

Abstract

Highly regio- and stereoselective ortho-vinylation of β-naphthols has been accomplished via CF3–π-allyl Pd-complex for the first time. Next, one-pot synthesis of CF3-naphtho[2,1-b]furans is developed through a oxidative radical cyclization reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01429C

Reference60 articles.

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4. Asymmetric Total Synthesis of Nigerone andent-Nigerone: Enantioselective Oxidative Biaryl Coupling of Highly Hindered Naphthols

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