K2S2O8 promoted metal-free direct C-alkylation of acetophenones with alcohols-Reference-Cited by-同舟云学术

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K₂S₂O₈ promoted metal-free direct C-alkylation of acetophenones with alcohols

Published:2023 Issue:48 Volume:21 Page:9519-9523
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Gautam Deepak¹,Gahlaut Puneet Singh¹,Pathak Shristi¹,Jana Barun¹^ORCID

Affiliation:

1. Organometallics and Supramolecular Chemistry Laboratory (OMSCL), Department of Chemistry, Malaviya National Institute of Technology Jaipur, Jaipur, Rajasthan-302017, India

Abstract

A metal-free synthetic methodology for the C-alkylation of acetophenones following a hydrogen borrowing-like pathway using the commercially available inorganic oxidant K2S2O8 in conjunction with KOtBu is reported.

Funder

Malaviya National Institute of Technology, Jaipur

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01526B

Reference25 articles.

1. Transition metal-free, iodide-mediated domino carbonylation–benzylation of benzyl chlorides with arylboronic acids under ambient pressure of carbon monoxide

2. Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

3. Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

4. Borrowing Hydrogen for Organic Synthesis

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