Synthesis of chroman-annulated cyclopropanols via photoinduced intramolecular [2 + 1]-cycloaddition of 2-allyloxybenzaldehydes

Author:

Zaitseva Elvira R.1,Opryshko Victoria E.1ORCID,Ivanov Dmitrii S.1,Mikhaylov Andrey A.1ORCID,Smirnov Alexander Yu.12ORCID,Baranov Mikhail S.12ORCID

Affiliation:

1. Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia

2. Pirogov Russian National Research Medical University, Ostrovitianov 1, 117997, Moscow, Russia

Abstract

2-Allyloxybenzaldehydes undergo [2 + 1] cycloadditions under 365 nm LED irradiation to form the corresponding chroman-fused cyclopropanols.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference38 articles.

1. P.Anastas and J.Warner , Green Chemistry: Theory and Practice , Oxford Univ Press , 1998

2. On Inventing Reactions for Atom Economy

3. Atom efficiency and catalysis in organic synthesis

4. The economies of synthesis

5. Catal. Org. Synth , ed. G. Brahmachari , The Royal Society Of Chemistry , 2017

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