Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of MII–CN–FeIII (M = Fe, Ru, Os)-Reference-Cited by-同舟云学术

Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of MII–CN–FeIII (M = Fe, Ru, Os)

Published:2014 Issue:46 Volume:43 Page:17453-17462
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Wang Yong¹²³⁴⁵,Ma Xiao¹²³⁴,Hu Shengmin¹²³⁴,Wen Yuehong¹²³⁴,Xue Zhenzhen¹²³⁴⁵,Zhu Xiaoquan¹²³⁴⁵,Zhang Xudong¹²³⁴,Sheng Tianlu¹²³⁴,Wu Xintao¹²³⁴

Affiliation:

1. State Key Laboratory of Structure Chemistry

2. Fujian Institute of Research on the Structure of Matter

3. Chinese Academy of Sciences

4. Fuzhou, China

5. School of Chemistry and Chemical Engineering

Abstract

Four 1D cyanide-bridged complexes [cis-M^II(L)₂(CN)₂Fe^III(salen)](PF₆) (3–6) have been synthesized, of which 3 and 4 are Class II mixed-valence complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02272F

Reference77 articles.

1. Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex

2. Spectroelectrochemical Studies on Mixed-Valence States in a Cyanide-Bridged Molecular Square,[RuII2FeII2(μ-CN)4(bpy)8](PF6)4⋅CHCl3⋅H2O

3. Synthesis, Characterization, and Intervalence Charge Transfer Properties of a Series of Rhenium(I)−Iron(III) Mixed-Valence Compounds

4. Absorption and MCD spectral studies of the decaammine(.mu.-dinitrogen-N,N')diosmium(5+) mixed-valence ion

5. Large Lattice Responses in a Mixed-Valence Prussian Blue Analogue Owing to Electronic and Spin Transitions Induced by X-ray Irradiation

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