An experimental and computational study of the reaction between pent-3-en-2-yl radicals and oxygen molecules: switching from pure stabilisation to pure decomposition with increasing temperature-Reference-Cited by-同舟云学术

An experimental and computational study of the reaction between pent-3-en-2-yl radicals and oxygen molecules: switching from pure stabilisation to pure decomposition with increasing temperature

Published:2022 Issue: Volume:238 Page:619-644
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Pekkanen Timo T.¹,Valkai László¹,Joshi Satya P.¹,Lendvay György²^ORCID,Heinonen Petri¹^ORCID,Timonen Raimo S.¹,Eskola Arkke J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Helsinki, P. O. Box 55 (A.I. Virtasen Aukio 1), 00014 Helsinki, Finland

2. Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Magyar Tudósok Krt. 2, Budapest H-1117, Hungary

Abstract

The phenomenological descriptions of complicated R + O2 ↔ RO2 → products reaction systems simplify significantly under pre-equilibrium conditions.

Funder

Magnus Ehrnroothin Säätiö

Helsingin Yliopisto

Academy of Finland

European Cooperation in Science and Technology

Országos Tudományos Kutatási Alapprogramok

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D2FD00031H

Reference44 articles.

1. Recent progress in gasoline surrogate fuels

2. Kinetic (T = 201–298 K) and Equilibrium (T = 320–420 K) Measurements of the C3H5 + O2 ⇆ C3H5O2 Reaction

3. An experimental and computational study of the reaction between 2-methylallyl radicals and oxygen molecules: optimizing master equation parameters with trace fitting

4. An experimental and master-equation modeling study of the kinetics of the reaction between resonance-stabilized (CH3)2CCHCH2 radical and molecular oxygen

5. Oxidation Kinetics and Thermodynamics of Resonance-Stabilized Radicals: The Pent-1-en-3-yl + O2 Reaction

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