At the crossroad of photochemistry and radiation chemistry: formation of hydroxyl radicals in diluted aqueous solutions exposed to ultraviolet radiation

Author:

Tomanová Kateřina1234,Precek Martin564ORCID,Múčka Viliam1234,Vyšín Luděk564ORCID,Juha Libor56478,Čuba Václav1234ORCID

Affiliation:

1. Czech Technical University in Prague

2. Faculty of Nuclear Sciences and Physical Engineering

3. 115 19 Prague 1

4. Czech Republic

5. Institute of Physics of the Czech Academy of Sciences

6. 182 21 Prague 8

7. Institute of Plasma Physics of the Czech Academy of Sciences

8. 182 00 Prague 8

Abstract

We provide evidence on the formation of ˙OH radicals via 253.7 nm photolysis of aqueous solutions, determine their quantum yields, and apply the knowledge to photo-induced formation of phospholipid hydroperoxides.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Grantová Agentura České Republiky

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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