Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(v)–Co(ii) cyanide single-chain magnet-Reference-Cited by-同舟云学术

Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(v)–Co(ii) cyanide single-chain magnet

Published:2018 Issue:1 Volume:9 Page:119-124
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Yuan-Zhu¹²³⁴¹,Dolinar Brian S.¹²³⁴^ORCID,Liu Shihao¹⁵⁶⁷,Brown Andrew J.¹²³⁴,Zhang Xuan¹²³⁴^ORCID,Wang Zhao-Xi¹²³⁴,Dunbar Kim R.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A & M University

3. College Station

4. USA

5. Southern University of Science and Technology

6. Shenzhen

7. P. R. China

Abstract

A new octacyanotungstate(v) singe chain magnet with an effective energy barrier of 39.7(3) cm⁻¹ is achieved by enforcing Ising-like magnetic anisotropy via introduction of trigonal distortion with a fac-tridentate capping ligand.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC02925J

Reference50 articles.

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5. C. Coulon , V.Pianet , M.Urdampilleta and R.Clérac , Molecular Nanomagnets , Springer-Verlag , Berlin Heidelberg , 2015 , pp. 143–184

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