Vibrational properties of heme-nitrosoalkane complexes in comparison with those of their HNO analogs, and reactivity studies towards nitric oxide and Lewis acids-Reference-Cited by-同舟云学术

Vibrational properties of heme-nitrosoalkane complexes in comparison with those of their HNO analogs, and reactivity studies towards nitric oxide and Lewis acids

Published:2024 Issue:33 Volume:53 Page:13906-13924
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Harland Jill B.¹,LaLonde Ashley B.¹^ORCID,Thomas Diamond J.¹,Castella Daniel G.¹^ORCID,Kampf Jeff W.¹,Zeller Matthias²,Alp E. Ercan³,Hu Michael Y.³^ORCID,Zhao Jiyong³,Lehnert Nicolai¹^ORCID

Affiliation:

1. Department of Chemistry and Department of Biophysics, University of Michigan, Ann Arbor, MI 48109, USA

2. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, USA

3. Advanced Photon Source, Argonne National Laboratory, Illinois 60439, USA

Abstract

Six-coordinate heme-RNO complexes, [Fe(Porph)(L)(RNO)] (Porph = TPP, 3,5-Me-BAFP; R= iPr, Ph), were prepared and structurally and spectroscopically characterized. The reactivity of the complexes towards NO and different Lewis acids was then explored.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01632G

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