Redox control in palladium catalyzed norbornene and alkyne polymerization-Reference-Cited by-同舟云学术

Redox control in palladium catalyzed norbornene and alkyne polymerization

Published:2017 Issue:5 Volume:4 Page:795-800
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zou Wenping¹²³⁴⁵,Pang Wenmin¹²³⁴⁵,Chen Changle¹²³⁴⁵^ORCID

Affiliation:

1. CAS Key Laboratory of Soft Matter Chemistry

2. iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)

3. Department of Polymer Science and Engineering

4. University of Science and Technology of China

5. Hefei

Abstract

Switchable polymerization of norbornene, 5-norbornene-2-yl acetate and 1-chloro-1-octyne could be realized by using two palladium complexes (NHC)Pd(allyl)Cl (NHC = 1,3-Ar₂-naphthoquinimidazolylidene, Ar = 2,6-Me₂-C₆H₃, 2,6-ⁱPr₂-C₆H₃) bearing a redox-active naphthoquinone moiety.

Funder

Natural Science Foundation of Anhui Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QI/C6QI00562D

Reference56 articles.

1. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

2. Chain Walking: A New Strategy to Control Polymer Topology