ABAB-type phthalocyanines simultaneously bearing electron donating and electron accepting groups. Synthesis, spectroscopy, and structure

Author:

Cao Wei12345,Wang Kang12345,Ledoux-Rak Isabelle678910,Jiang Jianzhuang12345

Affiliation:

1. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials

2. Department of Chemistry

3. University of Science and Technology Beijing

4. Beijing 100083

5. China

6. Laboratoire de Photonique Quantique et Moleculaire

7. Institut d'Alembert

8. CNRS ULR 8537

9. ENS Cachan

10. 94235 Cachan Cedex

Abstract

Mg(trans-TPTCPc) was successfully prepared and structurally characterized, representing the first structurally characterized ABAB-type phthalocyanine compound simultaneously bearing electron-donating and electron-accepting groups.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

1. A. B. P. Lever and C. C.Leznoff, in Phthalocyanine: Properties and Applications, VCH, Weinheim, 1989–1996, vol. 1–4

2. N. B. McKeown , in Phthalocyanines Materials: Synthesis Structure and Function, Cambridge University Press, New York, 1998

3. K. M. Kadish , K. M.Smith and R.Guilard, in The Porphyrin Handbook, Academic Press, San Diego, 2000–2003, vol. 15–20

4. J. Jiang , Advances in Functional Phthalocyanine Materials, in Structure and Bonding, ed. D. M. P. Mingos, Springer, Heidelberg, 2010, vol. 135

5. Low Symmetry Phthalocyanines and Their Analogues

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