Regioselective transformation of 3-phosphoryl benzyne intermediates to diverse phosphorus-substituted arenes-Reference-Cited by-同舟云学术

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Regioselective transformation of 3-phosphoryl benzyne intermediates to diverse phosphorus-substituted arenes

Published:2022 Issue:35 Volume:46 Page:17049-17054
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Jing¹,Li Zenghui¹,You Gaoqiang²,Xu Liang²^ORCID,Gao Pin¹^ORCID,Rao Bin¹^ORCID

Affiliation:

1. School of Chemistry, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, Xi’an Jiaotong University, Xi’an 710049, P. R. China

2. School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi, 832003, China

Abstract

Pre-functionalized benzyne precursors 5, 6 and 10 bearing a phosphoryl group were efficiently synthesized via a phospho-Fries rearrangement reaction on gram scales, and directly proceed various transformations to poly-substituted organophosphorus arenes in high regioselectivity.

Funder

National Natural Science Foundation of China

Xi’an Jiaotong University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03638J

Reference39 articles.

1. o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors

2. Strategies toward Aryne Multifunctionalization via 1,2-Benzdiyne and Benzyne

3. Uncovering the Neglected Similarities of Arynes and Donor–Acceptor Cyclopropanes

4. Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds

5. Aryne multifunctionalization with benzdiyne and benztriyne equivalents

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