Reactivity of the carbodiphosphorane, (Ph3P)2C, towards main group metal alkyl compounds: coordination and cyclometalation-Reference-Cited by-同舟云学术

Reactivity of the carbodiphosphorane, (Ph3P)2C, towards main group metal alkyl compounds: coordination and cyclometalation

Published:2019 Issue:25 Volume:48 Page:9139-9151
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Quinlivan Patrick J.¹²³⁴,Shlian Daniel G.¹²³⁴,Amemiya Erika¹²³⁴,Parkin Gerard¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Columbia University

3. New York

4. USA

Abstract

The zerovalent carbodiphosphorane, (Ph₃P)₂C, reacts with Me₃Al and Me₃Ga to afford the adducts, [(Ph₃P)₂C]MMe₃ (M = Al, Ga), whereas Me₂Zn and Me₂Mg react to afford mononuclear and dinuclear cyclometalated derivatives.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00678H

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