Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: SN2@P or the novel SN2@Cl followed by SN2@C?-Reference-Cited by-同舟云学术

登录注册会员服务联系我们

Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: S_N2@P or the novel S_N2@Cl followed by S_N2@C?

Published:2022 Issue:15 Volume:12 Page:9130-9138
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Savoo Nandini¹,Rhyman Lydia¹²,Ramasami Ponnadurai¹²^ORCID

Affiliation:

1. Computational Chemistry Group, Department of Chemistry, Faculty of Science, University of Mauritius, Réduit 80837, Mauritius

2. Centre for Natural Product Research, Department of Chemical Sciences, University of Johannesburg, Doornfontein Campus, Johannesburg 2028, South Africa

Abstract

The proposed SN2 reactions of a hindered organophosphorus reactant with aliphatic and aromatic nucleophiles [Ye et al., Org. Lett., 2017, 19, 5384–5387] were studied theoretically in order to explain the observed stereochemistry of the products.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA00258B

Reference77 articles.

1. Synthesis of bifunctional P-chiral hydroxy phosphinates; lipase-catalyzed stereoselective acylation of ethyl (1-hydroxyalkyl)phenylphosphinates

2. M.Etō , Organophosphorus Pesticides: Organic and Biological Chemistry , CRC Press, Inc. , Boca Raton , 1979

3. Synthesis and anti-cancer activities of a pair of enantiomeric gold(I) complexes containing sulfanyl-substituted P-stereogenic phosphines

4. Preparation of Scalemic P-Chiral Phosphines and Their Derivatives

5. Recent developments in the asymmetric synthesis of Р-chiral phosphorus compounds

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370

www.globalauthorid.com

TOP