Towards understanding the color change of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide during gamma irradiation: an experimental and theoretical study

Author:

Wang Shuojue12345,Liu Junzi16738,Yuan Liyong910115,Cui Zhenpeng12345,Peng Jing12345,Li Jiuqiang12345,Zhai Maolin12345,Liu Wenjian16738

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. Department of Applied Chemistry

3. College of Chemistry and Molecular Engineering

4. Peking University

5. Beijing, P. R. China

6. Institute of Theoretical and Computational Chemistry

7. State Key Laboratory of Rare Earth Materials Chemistry and Applications

8. and Center for Computational Science and Engineering

9. Key laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials & Nanosafety

10. Institute of High Energy Physics

11. Chinese Academy of Sciences

Abstract

The radiation-induced color change of [BMIm][NTf2] originates from the formation of double bonds in cations and various associated species containing [BMIm-H2][NTf2].

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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