Generation and reactivity of the fragment ion [B12I8S(CN)]− in the gas phase and on surfaces-Reference-Cited by-同舟云学术

Generation and reactivity of the fragment ion [B₁₂I₈S(CN)]⁻ in the gas phase and on surfaces

Published:2024 Issue:9 Volume:149 Page:2573-2585
ISSN:0003-2654
Container-title:The Analyst
language:en
Short-container-title:Analyst

Author:

Kawa Sebastian¹^ORCID,Kaur Jaskiran²^ORCID,Knorke Harald¹^ORCID,Warneke Ziyan¹,Wadsack Myriam¹,Rohdenburg Markus¹^ORCID,Nierstenhöfer Marc³^ORCID,Jenne Carsten³^ORCID,Kenttämaa Hilkka²^ORCID,Warneke Jonas¹⁴^ORCID

Affiliation:

1. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, 04103, Leipzig, Germany

2. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA

3. Anorganische Chemie, Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, Gaußstr. 20, 42119, Wuppertal, Germany

4. Leibniz Institute of Surface Engineering (IOM), Permoserstr. 15, 04318, Leipzig, Germany

Abstract

CID fragmentation of the synthesized [B12I11(SCN)]2− ions yields [B12I8S(CN)]− ions. The reactivity of these ions was studied in the gas phase and in ion soft-landing experiments, where selectivity toward certain functional groups was discovered.

Funder

Volkswagen Foundation

Fonds der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/AN/D3AN02175K

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