Modulating structures to decouple thermoelectric transport leads to high performance in polycrystalline SnSe

Author:

Wang Yuping1ORCID,Bai Shulin1,Shi Haonan1,Cao Qian2,Qin Bingchao1ORCID,Zhao Li-Dong1ORCID

Affiliation:

1. School of Materials Science and Engineering, Beihang University, Beijing 100191, China

2. Huabei Cooling Device Co. Ltd, Hebei 065400, China

Abstract

Introducing AgInSe2 modifies the crystal and band structures to facilitate electrical transport of SnSe, and Ge alloying further depresses phonon transport. The effective phonon-electron decoupling leads to an ultrahigh ZT ∼ 1.6 at 773 K.

Funder

Higher Education Discipline Innovation Project

National Key Research and Development Program of China

National Natural Science Foundation of China

Beijing Municipal Natural Science Foundation

Science Fund for Distinguished Young Scholars of Fujian Province

National Postdoctoral Program for Innovative Talents

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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