A non-photochemical route to synthesize simple benzo[1,2-b:4,3-b′]dithiophenes: FeCl3-mediated cyclization of dithienyl ethenes

Author:

Cauteruccio Silvia123,Dova Davide123,Graiff Claudia145,Carrara Claudio123,Doulcet Julien678,Stephenson G. Richard678,Licandro Emanuela123

Affiliation:

1. Dipartimento di Chimica

2. Università degli Studi di Milano

3. I-20133 Milano, Italy

4. Università degli Studi di Parma

5. Parma, Italy

6. School of Chemistry

7. University of East Anglia

8. Norwich, UK

Abstract

The FeCl3-mediated cyclization of α,α′-disubstituted Z-alkenes as a general and non-photochemical route to synthesize benzo[1,2-b:4,3-b′]dithiophene derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference46 articles.

1. Synthetic Principles for Bandgap Control in Linear π-Conjugated Systems

2. T. A. Skotheim and J. R.Reynolds , in Conjugated Polymers: Theory, Synthesis, Properties, and Characterization (Handbook of Conducting Polymers) , ed. T. A. Skotheim and J. R. Reynolds , CRC Press LLC. , Boca Raton, FL , 3rd edn, 2007

3. Molecular Bulk Heterojunctions: An Emerging Approach to Organic Solar Cells

4. Backbone Curvature in Polythiophenes

5. Benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers: band gap and energy level control and their application in polymer solar cells

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