Diversified magnetic behaviors of new nickel(ii) and copper(ii) azido coordination polymers templated by diethyl or triethyl amines

Author:

Zeng Ying12345,Liu Sui-Jun6745ORCID,Liu Cai-Ming89101112,Xie Yong-Rong12345,Du Zi-Yi12345

Affiliation:

1. Key Laboratory of Jiangxi University for Functional Materials Chemistry

2. College of Chemistry and Chemical Engineering

3. Gannan Normal University

4. Ganzhou 341000

5. P. R. China

6. School of Metallurgy and Chemical Engineering

7. Jiangxi University of Science and Technology

8. Beijing National Laboratory for Molecular Sciences

9. Center for Molecular Science

10. Institute of Chemistry

11. Chinese Academy of Sciences

12. Beijing

Abstract

The reactions of NiII or CuII ions with N3 anions in the presence of templated diethyl or triethyl amines afford three new azido-bridged coordination polymers, which exhibit metamagnetism, spin glass and canted ferromagnetism, respectively.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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